MERCK 106371 Sodium borohydride for analysis. CAS No. 16940-66-2, EC Number 241-004-4
MERCK

MERCK 106371 Sodium borohydride for analysis. CAS No. 16940-66-2, EC Number 241-004-4

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KİMYASAL ÜRÜNLER
Stok Kodu
M.106371.0100
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212,69 EUR + KDV
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Description
Catalogue Number 106371
Synonyms Sodium tetrahydridoborate
Product Information
CAS number 16940-66-2
EC number 241-004-4
Hill Formula H₄BNa
Chemical formula NaBH₄
Molar Mass 37.83 g/mol
HS Code 2850 00 20
Applications
Application Sodium borohydride for analysis. CAS No. 16940-66-2, EC Number 241-004-4.
Physicochemical Information
Boiling point 500 °C (decomposition)
Density 1.07 g/cm3 (20 °C)
Explosion limit 3.02 %(V)
Flash point 69 °C not applicable
Ignition temperature 220 °C
Melting Point >360 °C (slow decomposition)
pH value 11 (10 g/l, H₂O, 20 °C)
Vapor pressure <1 hPa (25 °C)
Bulk density 350 - 500 kg/m3
Toxicological Information
LD 50 oral LD50 Rat 160 mg/kg
LD 50 dermal LD50 Rabbit 230 mg/kg
Safety Information according to GHS
Hazard Pictogram(s)



Hazard Statement(s) H360FD: May damage fertility. May damage the unborn child.
H260: In contact with water releases flammable gases which may ignite spontaneously.
H301: Toxic if swallowed.
H314: Causes severe skin burns and eye damage.
EUH014: Reacts violently with water.
Precautionary Statement(s) P201: Obtain special instructions before use.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
P402 + P404: Store in a dry place. Store in a closed container.
Signal Word Danger
RTECS ED3325000
Storage class 4.3 Hazardous materials, which set free flammable gases upon contact with water
WGK WGK 2 water endangering
Disposal 26
Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
Safety Information
Hazard Symbols Toxic
Flammable
Corrosive
Categories of danger highly flammable, toxic, corrosive
R Phrase R 60-61-25-14/15-34
May impair fertility.May cause harm to the unborn child.Also toxic if swallowed.Reacts violently with water, liberating extremely flammable gases.Causes burns.
S Phrase S 14-26-36/37/39-43-45-53
Keep away from oxidising and acidic substances as well as heavy-metal compounds.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of fire, use sand. Never use water.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid exposure - obtain special instructions before use.
Storage and Shipping Information
Storage Storage temperature: no restrictions.
Transport Information
Declaration (railroad and road) ADR, RID UN 1426 , 4.3, I
Declaration (transport by air) IATA-DGR UN 1426 , 4.3, I
Declaration (transport by sea) IMDG-Code UN 1426 , 4.3, I
Specifications
Assay (oxidimetric) ≥ 96.0 %
Identity passes test
Chloride (Cl) ≤ 0.5 %
Sulphate (SO₄) ≤ 0.005 %
Heavy metals (as Pb) ≤ 0.005 %
As (Arsenic) ≤ 0.001 %
Bi (Bismuth) ≤ 0.0005 %
Fe (Iron) ≤ 0.005 %
Hg (Mercury) ≤ 0.00001 %
Sb (Antimony) ≤ 0.005 %
Se (Selenium) ≤ 0.0002 %
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MERCK 106371 Sodium borohydride for analysis. CAS No. 16940-66-2, EC Number 241-004-4 M.106371.0100
MERCK 106371 Sodium borohydride for analysis. CAS No. 16940-66-2, EC Number 241-004-4

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